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Wir sind gerne für Sie daThis thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
Produkteigenschaften
- Artikelnummer: 9789811092473
- Medium: Buch
- ISBN: 978-981-10-9247-3
- Verlag: Springer Nature Singapore
- Erscheinungstermin: 07.07.2018
- Sprache(n): Englisch
- Auflage: Softcover Nachdruck of the original 1. Auflage 2017
- Serie: Springer Theses
- Produktform: Kartoniert, Previously published in hardcover
- Gewicht: 248 g
- Seiten: 141
- Format (B x H x T): 155 x 235 x 9 mm
- Ausgabetyp: Kein, Unbekannt