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Physical & Chemical Equilibrium

Medium: Buch
ISBN: 978-0-471-07170-9
Verlag: WILEY
Erscheinungstermin: 31.12.2001
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Eine technisch exakte Darstellung des physikalischen und chemischen Gleichgewichts erwartet den Leser in diesem Buch. Mathematische Herleitungen sind so einfach wie möglich gehalten. Beim Verständnis der Algorithmen helfen zahlreiche durchgerechnete Beispiele. Der Schwerpunkt liegt auf den physikalischen Grundlagen von Rechenverfahren in der Industrie. Berücksichtigt werden auch neueste Aspekte der Ingenieurtechnik, zum Beispiel Gleichgewichte in wässriger Lösung und in Elektrolyten oder der osmotische Druck. Mit einer Sammlung physikalischer Daten!

The first accessible, in-depth, and up-to-date exploration of physical and chemical equilibrium
This textbook provides a thorough introduction to the basic tools of chemical engineers-physical and chemical equilibrium. It is a text for second course thermodynamics students in chemical engineering. While traditional texts combine this topic with the first thermodynamics course, Physical and Chemical Equilibrium for Chemical Engineers gives chemical engineers the rigorous yet clear treatment more advanced students and chemical engineers require.
Professor Noel de Nevers provides readers with a technically accurate and rigorous look at physical and chemical equilibrium-often called "solution thermodynamics." He presents the material in an accessible format that uses simple mathematics without sacrificing rigor. The text shows where "modern" terminology differs from "classic" terminology and covers different standard states, a common stumbling block for both students and professionals.
Emphasis is placed on such up-to-date topics as aqueous solutions, electrolytes, and osmotic pressure, all of which play an important role in modern industrial processes and biotechnology. Unique coverage includes:
* Minimization of Gibbs Free Energy
* Vapor Pressure, the Clapayron Equation, and Single Pure Species Phase Equilibrium
* Partial Molal Properties
* Fugacity, Ideal and Non-Ideal Solutions, Activity, and Activity Coefficient
* The Phase Rule
With numerous physical data and commercial process examples, Physical and Chemical Equilibrium for Chemical Engineers goes beyond the fundamentals to extend the mastery of both students and practicing chemical engineers in this critical area.


Produkteigenschaften


  • Artikelnummer: 9780471071709
  • Medium: Buch
  • ISBN: 978-0-471-07170-9
  • Verlag: WILEY
  • Erscheinungstermin: 31.12.2001
  • Sprache(n): Englisch
  • Auflage: 1. Auflage 2001
  • Produktform: Gebunden
  • Gewicht: 1128 g
  • Seiten: 474
  • Format (B x H x T): 183 x 260 x 31 mm
  • Ausgabetyp: Kein, Unbekannt
  • Nachauflage: 978-0-470-92710-6
Autoren/Hrsg.

Autoren

Preface.

About the Author.

Nomenclature.

Introduction to Equilibrium.

Basic Thermodynamics.

The Simplest Phase Equilibrium Examples and Some Simple Estimating Rules.

Minimization of Gibbs Free Energy.

Vapor Pressure, The Clapeyron Equation, and Single Pure Chemical Species Phase Equilibrium.

Partial Molal Properties.

Fugacity, Ideal Solutions, Activity, Activity Coefficient.

Vapor-Liquid Equilibrium (VLE) at Low Pressures.

Correlating and Predicting Nonideal VLE.

Vapor Liquid Equilibrium (VLE) at High Pressures.

Liquid-Liquid, Liquid-Solid and Gas-Solid Equilibrium.

Chemical Equilibrium.

Equilibrium in Complex Chemical Reactions.

Equilibrium with Gravity or Centrifugal Force, Osmotic Equilibrium, Equilibrium with Surface Tension.

The Phase Rule.

Appendix A: Useful Tables and Charts.

Appendix B: Equilibrium at Other Constraints, Approach to Equilibrium.

Appendix C: The Mathematics of Fugacity, Ideal Solutions, Activity and Activity Coefficients.

Appendix D: Equations of State for Liquids and Solids Well Below Their Critical Temperatures.

Appendix E: Free Energy of Formation Values.

Appendix F: Calculation of Fugacities from Pressure-Explicit EOSs.

Appendix G: Answers to Selected Problems.

Index.